Publications 2020-

Enantioselective Organocatalysis and Superacid Activation: Challenges and Opportunities. DOI: 10.1002/chem.202300440. B. Michelet, A. Martin-Mingot, J. Rodriguez, S. Thibaudeau, D. Bonne, Chem. Eur. J. 2023, e202300440.

Exploring F/CF3 substituted oxocarbenium ions for the diastereoselective assembly of highly substituted tetrahydrofuran skeletons. DOI: 10.1039/D2CC06521E. A. J. Fernandes, B. Michelet, A. Panossian, A. Martin-Mingot, F. R. Leroux, S. Thibaudeau, Chem. Commun. 2023, 59, 4083-4086.

Hidden Heptacyclic Chiral N-Acyl Iminium Ions: A New Entry to Enantioenriched Polycyclic Azepanes and Azocanes by Superacid-Promoted Intramolecular Pictet-Spengler Reaction. DOI: 10.1002/chem.202200432. Y. Reviriot, B. Michelet, R. Beaud, A. Martin-Mingot, F. Guégan, S. Thibaudeau, J. Rodriguez, D. Bonne, Chem. A. Eur J. 2022, 28, e202200432.

Superacid-Mediated Late-Stage Aromatic Polydeuteration of Pharmaceuticals. DOI: 10.1002/chem.202201583. E. Appert, A. Martin-Mingot, O. Karam, F. Zunino, B. Michelet, F. Bouazza, S. Thibaudeau, Chem. A Eur. J. 2022, 28, e202201583.

Direct Superacid-Promoted Difluoroethylation of Aromatics. DOI: 1002/chem.202103926. M. Artault, K. Vitse, A. Martin-Mingot, S. Thibaudeau, Chem. A Eur. J. 2022, 28, e202103926.

Modulating the Efficacy of Carbonic Anhydrase Inhibitors through Fluorine Substitution. DOI: 10.1002/anie.20210321. E. Berrino, B. Michelet, A. Martin-Mingot, F. Carta, C. T. Supuran, S. Thibaudeau,  Angew. Chem. Int. Ed. 2021, 60, 23068-23082.

Formation of Synthetically relevant CF3-Substitute Phenonium Ions in Superacid Media. DOI : 10.1039/d1ra04901a. A. J. Fernandes; B. Michelet, A. Panossian, A. Martin-Mingot, F. R. Leroux, S. Thibaudeau,  RCS Adv., 2021, 11, 25695-25699.

Complementary Site-Selective Sulfonylation of Aromatic Amines by Superacid Activation. DOI: 10.1021/acs.orglett.1c00994. P. Bourbon, E. Appert, A. Martin-Mingot, B. Michelet, S. Thibaudeau, Org. Lett. 2021, 23, 4115-4120.

Glycosyl Oxocarbenium Ions: Structure, Conformation, Reactivity, and Interactions. DOI:10.1021/acs.accounts.1c00021. A. Franconetti, A. Ardá, J. L. Asensio, Y. Blériot, S. Thibaudeau, J. Jiménez-Barbero. Acc. Chem. Res. 2021, 54, 2552-2564.

CF3-substituted carbocations: underexploited intermediates with great potential in modern synthetic chemistry. DOI:10.3762/bjoc.17.32. A. J. Fernandes, A. Panossian, B. Michelet, A. Martin-Mingot, F. R. Leroux, S. Thibaudeau, Beilstein J. Org. Chem. 2021, 17, 343–37.

Insight into the Ferrier Rearrangement by Combining Flash Chemistry and Superacids. DOI: 10.1002/ange.202010175. N. Bhuma, L. Lebedel, H. Yamashita, Y. Shimizu, Z. Abada, A. Ardá, J. Désiré, B. Michelet, A. Martin-Mingot, A. Abou-Hassan, M. Takumi, J. Marrot, J. Jiménez-Barbero, A. Nagaki, Y. Blériot, S. Thibaudeau,  Angew. Chem. Int. Ed. 2021, 60, 2036-2041.

Evidence and exploitation of dicationic ammonium–nitrilium superelectrophiles: direct synthesis of unsaturated piperidinones DOI: 10.1039/d0cc02910f. T. Cantin, Y. Morgenstern, A. Mingot, A. Kornath, S. Thibaudeau, Chem. Commun. 2020, 56, 11110-11113.

Superelectrophilic Csp3–H bond fluorination of aliphatic amines in superacid: the striking role of ammonium–carbenium dications. DOI: 10.1039/d0cc02081h. M. Artault, N. Moktari, T. Cantin, A. Martin-Mingot, S. Thibaudeau, Chem. Commun. 2020, 56, 5905-5908.

Sequential Suzuki–Miyaura Coupling/Lewis Acid-Catalyzed Cyclization: An Entry to Functionalized Cycloalkane-Fused Naphthalenes. DOI: 10.1021/acs.orglett.0c02020. C. Mahecha-Mahecha, F. Lecornué, S. Akinari, T. Charote, D. Gamba-Sánchez, T. Ohwada, S. Thibaudeau, Org. Lett. 2020, 16, 6267-6271.

Access to Optically Pure Benzosultams by Superelectrophilic Activation. DOI : 10.1021/acs.orglett.0c01301. B. Michelet, U. Castelli, E. Appert, M. Boucher, K. Vitse, J. Marrot, J. Guillard, A. Martin-Mingot, S. Thibaudeau, Org. Lett. 2020, 13, 4944-4948.

Complementary Site‐Selective Halogenation of Nitrogen‐Containing (Hetero)Aromatics with Superacids. DOI: 10.1002/chem.202000902.  A. Mamontov, A. Martin-Mingot, B. Métayer, O. Karam, F. Zunino, F. Bouazza, S. Thibaudeau, Chem. Eur. J. 2020, 26, 10411-10416.