Bastien Michelet

  • Bastien Michelet
Fil d'ariane
    • CNRS Researcher (CR)

    Publications HAL

    Article dans une revue (37 documents)
    • Delphine Pichon-Barré, Hélène Carreyre, Frédéric Lecornué, Agnès Martin-Mingot, Bastien Michelet, et al.. Activation of N-containing olefins and alkynes with superacids. Comptes Rendus. Chimie, 2025, 28, pp.727-754. ⟨10.5802/crchim.416⟩. ⟨hal-05321953⟩
    • Hao Wu, Yuko Otani, Ying Zhou, Bastien Michelet, Sebastien Thibaudeau, et al.. Benzophenone-Based Phenylogous Peptide Linkage via Friedel–Crafts Acylation. Organic Letters, In press, ⟨10.1021/acs.orglett.5c03833⟩. ⟨hal-05321949⟩
    • Mélissa Longuet, Fabien Naullet, Alexandre Pérochon, Agnès Martin-Mingot, Frédéric Guégan, et al.. Regulating the Acidity of HF/Pyridine Media to Control the Chemodivergent Fluoro- and Hydro-Heteroalkylation of Olefins. Journal of the American Chemical Society, 2025, 147 (32), pp.29079-29087. ⟨10.1021/jacs.5c07526⟩. ⟨hal-05221813⟩
    • Mathilde Armand, Alba Nin-Hill, Ana Ardá, Emanuela Berrino, Jérôme Désiré, et al.. Glycosylium Ions in Superacid Mimic the Transition State of Enzyme Reactions. Journal of the American Chemical Society, 2024, 146 (47), pp.32618-32626. ⟨10.1021/jacs.4c11677⟩. ⟨hal-05326476⟩
    • Emanuela Berrino, Bastien Michelet, Kassandra Vitse, Alessio Nocentini, Gianluca Bartolucci, et al.. Superacid-Synthesized Fluorinated Diamines Act as Selective hCA IV Inhibitors. Journal of Medicinal Chemistry, 2024, ⟨10.1021/acs.jmedchem.4c01795⟩. ⟨hal-04753033⟩
    • Paul Bourbon, Kassandra Vitse, Agnès Martin-Mingot, Hugo Geindre, Frédéric Guégan, et al.. Leveraging long-lived arenium ions in superacid for meta-selective methylation. Nature Communications, 2024, 15 (1), pp.7435. ⟨10.1038/s41467-024-49421-8⟩. ⟨hal-04680872⟩
    • Mélissa Longuet, Kassandra Vitse, Agnès Martin-Mingot, Bastien Michelet, Frédéric Guégan, et al.. Determination of the Hammett Acidity of HF/Base Reagents. Journal of the American Chemical Society, 2024, ⟨10.1021/jacs.4c02344⟩. ⟨hal-04552304⟩
    • Mathilde Armand, Alba Nin-Hill, Ana Ardá, Emanuela Berrino, Jérôme Désiré, et al.. Glycosylium Ions in Superacid Mimic the Transition State of Enzyme Reactions. Journal of the American Chemical Society, 2024, 146 (47), pp.32618-32626. ⟨10.1021/jacs.4c11677⟩. ⟨hal-05176253⟩
    • Anthony J Fernandes, Bastien Michelet, Armen Panossian, Agnès Martin-Mingot, Frédéric R Leroux, et al.. Exploring F/CF3 substituted oxocarbenium ions for the diastereoselective assembly of highly substituted tetrahydrofurans. Chemical Communications, 2023, 59 (27), pp.4083-4086. ⟨10.1039/d2cc06521e⟩. ⟨hal-04046996⟩
    • Maxime Artault, Thomas Cantin, Mélissa Longuet, Kassandra Vitse, Christ Daniel Matatu Mbengo, et al.. Exploring Superacid‐Promoted Skeletal Reorganization of Aliphatic Nitrogen‐Containing Compounds. Angewandte Chemie International Edition, 2023, 63 (1), pp.e202316458. ⟨10.1002/anie.202316458⟩. ⟨hal-04520297⟩
    • Bastien Michelet, Agnès Martin-Mingot, Jean Rodriguez, Sébastien Thibaudeau, Damien Bonne. Enantioselective Organocatalysis and Superacid Activation: Challenges and Opportunities. Chemistry - A European Journal, 2023, 29 (35), pp.e202300440. ⟨10.1002/chem.202300440⟩. ⟨hal-04047011⟩
    • Clément Jacob, Hajar Baguia, Amaury Dubart, Samuel Oger, Pierre Thilmany, et al.. A general synthesis of azetidines by copper-catalysed photoinduced anti-Baldwin radical cyclization of ynamides. Nature Communications, 2022, 13 (1), pp.560. ⟨10.1038/s41467-022-28098-x⟩. ⟨hal-03798007⟩
    • Yasmin Reviriot, Bastien Michelet, Rodolphe Beaud, Agnès Martin-Mingot, Frédéric Guégan, et al.. Hidden Heptacyclic Chiral N-Acyl Iminium Ions: a New Entry to Enantioenriched Polycyclic Azepanes and Azocanes by Superacid-Promoted Intramolecular Pictet-Spengler Reaction. Chemistry - A European Journal, 2022, 28 (25), pp.e202200432. ⟨10.1002/chem.202200432⟩. ⟨hal-03769652⟩
    • Emeline Appert, Agnès Martin-Mingot, Omar Karam, Fabien Zunino, Bastien Michelet, et al.. Superacid‐Mediated Late‐Stage Aromatic Polydeuteration of Pharmaceuticals. Chemistry - A European Journal, 2022, 28 (49), pp.e202201583. ⟨10.1002/chem.202201583⟩. ⟨hal-03769665⟩
    • Emanuela Berrino, Bastien Michelet, Agnès Martin-Mingot, Fabrizio Carta, Claudiu T Supuran, et al.. Modulating the Efficacy of Carbonic Anhydrase Inhibitors through Fluorine Substitution. Angewandte Chemie International Edition, 2021, 60 (43), pp.23068-23082. ⟨10.1002/anie.202103211⟩. ⟨hal-03358401⟩
    • Paul Bourbon, Emeline Appert, Agnès Martin-Mingot, Bastien Michelet, Sébastien Thibaudeau. Complementary Site-Selective Sulfonylation of Aromatic Amines by Superacid Activation. Organic Letters, 2021, 23 (11), pp.4115-4120. ⟨10.1021/acs.orglett.1c00994⟩. ⟨hal-03358394⟩
    • Naresh Bhuma, Ludivine Lebedel, Hiroki Yamashita, Yutaka Shimizu, Zahra Abada, et al.. Insight into the Ferrier rearrangement by combining flash chemistry and superacids. Angewandte Chemie International Edition, 2021, 60 (4), pp.2036-2041. ⟨10.1002/anie.202010175⟩. ⟨hal-03007376⟩
    • Anthony J Fernandes, Armen Panossian, Bastien Michelet, Agnès Martin-Mingot, Frédéric Leroux, et al.. CF3-substituted carbocations: underexploited intermediates with great potential in modern synthetic chemistry. Beilstein Journal of Organic Chemistry, 2021, 17, pp.343-378. ⟨10.3762/bjoc.17.32⟩. ⟨hal-03154651⟩
    • Anthony J Fernandes, Bastien Michelet, Armen Panossian, Agnès Martin-Mingot, Frédéric R. Leroux, et al.. Formation of synthetically relevant CF3-substituted phenonium ions in superacid media. RSC Advances, 2021, 11 (41), pp.25695 - 25699. ⟨10.1039/d1ra04901a⟩. ⟨hal-03325280⟩
    • Bastien Michelet, Ugo Castelli, Emeline Appert, Maude Boucher, Kassandra Vitse, et al.. Access to Optically-Pure Benzosultams by Superelectrophilic Activation. Organic Letters, 2020, 22 (13), pp.4944-4948. ⟨10.1021/acs.orglett.0c01301⟩. ⟨hal-03016554⟩
    • Rodolphe Beaud, Bastien Michelet, Yasmin Reviriot, Agnès Martin-Mingot, Jean Rodriguez, et al.. Enantioenriched Methylene-Bridged Benzazocanes Synthesis by Organocatalytic and Superacid Activations. Angewandte Chemie International Edition, 2020, 59 (3), pp.1279-1285. ⟨10.1002/anie.201912043⟩. ⟨hal-02436747⟩
    • Ayaka Uehara, Sandra Olivero, Bastien Michelet, Agnès Martin-Mingot, Sébastien Thibaudeau, et al.. Direct and Selective C-H Carbamoylation of (Hetero)aromatics with TMSOTf-Activated Carbamoyl Chloride. European Journal of Organic Chemistry, 2019, 2019 (1), pp.46-49. ⟨10.1002/ejoc.201801338⟩. ⟨hal-03007761⟩
    • Hajar Baguia, Christopher Deldaele, Bastien Michelet, Jérôme Beaudelot, Cédric Theunissen, et al.. [(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst. Journal of visualized experiments : JoVE, 2019, 147, ⟨10.3791/59739⟩. ⟨hal-03007750⟩
    • Bastien Michelet, Hélène Carreyre, Frédéric Lecornué, Agnès Mingot, Sébastien Thibaudeau. Superelectrophilic activation in superacid HF/SbF5: Expanding molecular diversity in nitrogen-containing compounds series by fluorination. Journal of Fluorine Chemistry, 2018, 214, pp.68-79. ⟨10.1016/j.jfluchem.2018.04.017⟩. ⟨hal-03007791⟩
    • Christopher Deldaele, Bastien Michelet, Hajar Baguia, Sofia Kajouj, Eugenie Romero, et al.. A General Copper-based Photoredox Catalyst for Organic Synthesis: Scope, Application in Natural Product Synthesis and Mechanistic Insights. CHIMIA, 2018, 72 (9), pp.621-629. ⟨10.2533/chimia.2018.621⟩. ⟨hal-03007774⟩
    • Hajar Baguia, Christopher Deldaele, Eugénie Romero, Bastien Michelet, Gwilherm Evano. Copper-Catalyzed Photoinduced Radical Domino Cyclization of Ynamides and Cyanamides: A Unified Entry to Rosettacin, Luotonin A, and Deoxyvasicinone. Synthesis: Journal of Synthetic Organic Chemistry, 2018, 50 (15), pp.3022-3030. ⟨10.1055/s-0037-1610134⟩. ⟨hal-03007805⟩
    • Bastien Michelet, Christopher Deldaele, Sofia Kajouj, Cécile Moucheron, Gwilherm Evano. A General Copper Catalyst for Photoredox Transformations of Organic Halides. Organic Letters, 2017, 19 (13), pp.3576-3579. ⟨10.1021/acs.orglett.7b01518⟩. ⟨hal-03007815⟩
    • Gwilherm Evano, Bastien Michelet, Chunyang Zhang. The anionic chemistry of ynamides: A review. Comptes Rendus. Chimie, 2017, 20 (6), pp.648-664. ⟨10.1016/j.crci.2016.12.002⟩. ⟨hal-03007821⟩
    • Bastien Michelet, David Lebœuf, Christophe Bour, Karel Škoch, Filip Horký, et al.. Catalytic Activity of Gold(I) Complexes with Hemilabile P,N Ligands. ChemPlusChem, 2017, 82 (3), pp.442-448. ⟨10.1002/cplu.201600562⟩. ⟨hal-03007828⟩
    • David Lebøeuf, Lucile Marin, Bastien Michelet, Alejandro Perez-Luna, Régis Guillot, et al.. Harnessing the Lewis Acidity of HFIP through its Cooperation with a Calcium(II) Salt: Application to the Aza-Piancatelli Reaction. Chemistry - A European Journal, 2016, 22 (45), pp.16165--16171. ⟨10.1002/chem.201603592⟩. ⟨hal-01712359⟩
    • Gwilherm Evano, Nicolas Blanchard, Guillaume Compain, Alexis Coste, Charles Demmer, et al.. A Journey in the Chemistry of Ynamides: From Synthesis to Applications. Chemistry Letters, 2016, 45 (6), pp.574-585. ⟨10.1246/cl.160260⟩. ⟨hal-03007853⟩
    • Bastien Michelet, Shun Tang, Guillaume Thiery, Julien Monot, Huijing Li, et al.. Catalytic applications of [IPr·GaX 2 ][SbF 6 ] and related species. Organic Chemistry Frontiers, 2016, 3 (12), pp.1603-1613. ⟨10.1039/C6QO00470A⟩. ⟨hal-03007837⟩
    • Bastien Michelet, Guillaume Thiery, Christophe Bour, Vincent Gandon. Non-Innocent Behavior of Substrate Backbone Esters in Metal-Catalyzed Carbocyclizations and Friedel–Crafts Reactions of Enynes and Arenynes. Journal of Organic Chemistry, 2015, 80 (21), pp.10925-10938. ⟨10.1021/acs.joc.5b02052⟩. ⟨hal-03007863⟩
    • David Lebœuf, Marc Presset, Bastien Michelet, Christophe Bour, Sophie Bezzenine-Lafollée, et al.. Ca II -Catalyzed Alkenylation of Alcohols with Vinylboronic Acids. Chemistry - A European Journal, 2015, 21 (31), pp.11001-11005. ⟨10.1002/chem.201501677⟩. ⟨hal-03007865⟩
    • Bastien Michelet, Jean-Rémy Colard-Itté, Guillaume Thiery, Régis Guillot, Christophe Bour, et al.. Dibromoindium( iii ) cations as a π-Lewis acid: characterization of [IPr·InBr 2 ][SbF 6 ] and its catalytic activity towards alkynes and alkenes. Chemical Communications, 2015, 51 (34), pp.7401-7404. ⟨10.1039/C5CC00740B⟩. ⟨hal-03007870⟩
    • Bastien Michelet, Christophe Bour, Vincent Gandon. Gallium-Assisted Transfer Hydrogenation of Alkenes. Chemistry - A European Journal, 2014, 20 (44), pp.14488-14492. ⟨10.1002/chem.201404139⟩. ⟨hal-03007877⟩
    • Shun Tang, Julien Monot, Ahmad El-Hellani, Bastien Michelet, Régis Guillot, et al.. Cationic Gallium(III) Halide Complexes: A New Generation of π-Lewis Acids. Chemistry - A European Journal, 2012, 18 (33), pp.10239-10243. ⟨10.1002/chem.201201202⟩. ⟨hal-03007906⟩
    Communication dans un congrès (5 documents)
    • Bastien Michelet. From strong acids to superacids: exploitation in organic synthesis. Invited lecture ICGM, Jun 2025, Montpellier, France. ⟨hal-05574031⟩
    • Bastien Michelet. Synthèse organique en milieu HF : récents développements. 4ème Colloque Français de chimie du Fluor, May 2024, Le Mans, France. ⟨hal-05574028⟩
    • Bastien Michelet. Exploitation de milieux superacides en synthèse organique. Journées des chargé∙e∙s de recherche de l’Institut de chimie du CNRS, Oct 2023, Paris, France. ⟨hal-05574022⟩
    • Bastien Michelet. Leveraging long-lived arenium ions in superacid for meta-selective Friedel-Crafts methylation. Groupe d’Études en Chimie Organique (GECO63), Aug 2023, Kerjouanno, France. ⟨hal-05574020⟩
    • Bastien Michelet. Organic synthesis in superacid: recent developments. IXe Demi-journée scientifique de l’iSm2 - 2021, Dec 2021, Marseille, France. ⟨hal-05574016⟩
    Image (2 documents)
    • Bastien Michelet, Agnès Martin-Mingot, Jean Rodriguez, Sébastien Thibaudeau, Damien Bonne. Enantioselective Organocatalysis and Superacid Activation: Challenges and Opportunities. France. 2023. ⟨hal-04414104⟩
    • Rodolphe Beaud, Bastien Michelet, Yasmin Reviriot, Agnès Martin-Mingot, Jean Rodriguez, et al.. Enantioenriched Methylene-Bridged Benzazocanes Synthesis by Organocatalytic and Superacid Activations. Illustration. France. 2020. ⟨hal-02436606⟩
    Chapitre d'ouvrage (2 documents)
    • Frédéric Lecornué, Bastien Michelet. Four-Membered Rings With Two Nitrogen Atoms. David StC Black; Janine Cossy; Christian V. Stevens. Comprehensive Heterocyclic Chemistry IV, Volume 2: Four-membered Heterocycles, and all Fused Systems with a Four-membered Heterocyclic Ring, 2, Elsevier, pp.403-457, 2022, 978-0-12-818656-5. ⟨10.1016/B978-0-12-818655-8.00153-0⟩. ⟨hal-03363494⟩
    • Masahiko Yamaguchi, Shigeki Matsunaga, Masakatsu Shibasaki, Bastien Michelet, Christophe Bour, et al.. Gallium Trichloride. Encyclopedia of Reagents for Organic Synthesis, John Wiley & Sons, Ltd, 2014, ⟨10.1002/047084289X.rn00118u.pub3⟩. ⟨hal-03007900⟩

    Bastien Michelet

    Research interest

    Superacid Chemistry – Hydrogen Fluoride

    Career

    • 2018-          CNRS researcher – IC2MP
    • 2017-2018 Post-doctoral fellow – University of Poitiers / IC2MP – Supervisor: Pr. S. Thibaudeau
    • 2015-2017 Post-doctoral fellow – Université Libre de Bruxelles – Supervisor: Pr. G. Evano
    • 2012-2015 PhD in Organic Chemistry – University Paris-Saclay / ICMMO – Supervisor: Pr. V. Gandon

     

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