Publications 2020

Insight into the Ferrier Rearrangement by Combining Flash Chemistry and Superacids. DOI: 10.1002/ange.202010175. N. Bhuma, L. Lebedel, H. Yamashita, Y. Shimizu, Z. Abada, A. Ardá, J. Désiré, B. Michelet, A. Martin-Mingot, A. Abou-Hassan, M. Takumi, J. Marrot, J. Jiménez-Barbero, A. Nagaki, Y. Blériot, S. Thibaudeau, Angew. Chem. Int. Ed. 2020, accepted article.

Evidence and exploitation of dicationic ammonium–nitrilium superelectrophiles: direct synthesis of unsaturated piperidinones DOI: 10.1039/d0cc02910f. T. Cantin, Y. Morgenstern, A. Mingot, A. Kornath, S. Thibaudeau, Chem. Commun. 2020, 56, 11110-11113.

Superelectrophilic Csp3–H bond fluorination of aliphatic amines in superacid: the striking role of ammonium–carbenium dications. DOI: 10.1039/d0cc02081h. M. Artault, N. Moktari, T. Cantin, A. Martin-Mingot, S. Thibaudeau, Chem. Commun. 2020, 56, 5905-5908.

Sequential Suzuki–Miyaura Coupling/Lewis Acid-Catalyzed Cyclization: An Entry to Functionalized Cycloalkane-Fused Naphthalenes. DOI: 10.1021/acs.orglett.0c02020. C. Mahecha-Mahecha, F. Lecornué, S. Akinari, T. Charote, D. Gamba-Sánchez, T. Ohwada, S. Thibaudeau, Org. Lett. 2020, 16, 6267-6271

Access to Optically Pure Benzosultams by Superelectrophilic Activation. DOI : 10.1021/acs.orglett.0c01301. B. Michelet, U. Castelli, E. Appert, M. Boucher, K. Vitse, J. Marrot, J. Guillard, A. Martin-Mingot, S. Thibaudeau, Org. Lett. 2020, 13, 4944-4948.

Complementary Site‐Selective Halogenation of Nitrogen‐Containing (Hetero)Aromatics with Superacids. DOI: 10.1002/chem.202000902.  A. Mamontov, A. Martin-Mingot, B. Métayer, O. Karam, F. Zunino, F. Bouazza, S. Thibaudeau, Chem. Eur. J. 2020, 26, 10411-10416.